The ideal gas law fails at low temperature and high-pressure because the volume occupied by the gas is quite small, so the inter-molecular distance between the molecules decreases.
Chemistry Exam 2 Flashcards – Quizlet
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Under what conditions does the ideal gas law fail?
At low pressure or high-temperature conditions, gas mixtures can be considered ideal gas mixtures for ease of calculation. When systems are not at low pressures or high temperatures, the gas particles are able to interact with one another; these interactions greatly inhibit the Ideal Gas Law’s accuracy.
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What makes the ideal gas law deviate?
The deviation of real gas from ideal gas behaviour occurs due to the assumption that if pressure increases the volume decreases. The volume will approach a smaller number but will not be zero because the molecules will occupy some space that cannot be compressed further.
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Why does the ideal gas law fail at high temperatures?
The ideal gas model tends to fail at lower temperatures or higher pressures, when intermolecular forces and molecular size becomes important. It also fails for most heavy gases, such as many refrigerants, and for gases with strong intermolecular forces, notably water vapor.
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Under what conditions is the ideal gas equation most accurate?
The ideal gas law is most accurate when the volume of gas particles is small compared to the space between them. It is also accurate when the forces between particles are not important. The ideal gas law breaks down at high pressures and low temperatures.
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What happens to ideal gas at high temperature?
Real gases approximate ideal gas behavior at relatively low density, low pressure, and high temperature. At high temperatures, the gas molecules have enough kinetic energy to overcome intermolecular forces, but at low temperatures, the gas has less kinetic energy and thus the intermolecular forces are more prominent.
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What causes ideal gas law to fail?
The ideal gas law fails at low temperature and high-pressure because the volume occupied by the gas is quite small, so the inter-molecular distance between the molecules decreases.
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Does ideal gas law work at high temperature?
The ideal gas laws work well at relatively low pressures and relatively high temperatures. When the pressure and temperature depart from these ranges, significant error can result from the use of the ideal gas laws.
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Why gases tend to behave non ideally at high pressure and low temperature?
Gases behave very non-ideally at low temperature and high pressure since slow-moving, closely-packed molecules are more likely to interact with each other.
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What are the two main factors for deviation of ideal gas law?
The main reason for deviation of gases from the ideal behavior is few assumptions of kinetic theory. These are. (i)there is no force of attraction between the molecules of gas. (ii)The volume of molecules of a gas is negligibly small in comparison to the volume of the gas.
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In which conditions does ideal gas Show deviation?
Deviation of gases from their ideal gas behaviour occurs when the molecules of a gas are cooled down to a point where they no longer possess sufficient kinetic energy to overcome attractive intermolecular forces.
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Under what conditions is the Ideal Gas Law most accurate?
The ideal gas law is most accurate when the volume of gas particles is small compared to the space between them (such as a small density). It is also accurate when the forces between particles are not important. The ideal gas law breaks down at high pressures and low temperatures.
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At what condition ideal gas equation is applicable?
The Ideal Gas Law is applicable at high temperature and low pressure only.
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At what conditions are gases most like ideal gases?
Gases are most ideal at high temperature and low pressure.
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